Publication date: 30 January 2026
Source: Journal of Metastable and Nanocrystalline Materials Vol. 43
Author(s): Rini Zaqiyah, Fadilah Wulan Cahyani, Lathifatul Lu'lu' Musyarrofah, Nandang Mufti, Silvi Rahmawati Wibowo
Low-cost and environmentally friendly energy storage is currently being extensively researched, with batteries being one of the primary focuses. However, many battery materials still involve hazardous substances during synthesis and are relatively high-cost. Therefore, this study aims to address these limitations by developing a battery using an alternative material, coalite, synthesized via the Hummer’s method. The primary objective is to investigate the effect of coalite carbonization temperature on the synthesis of reduced graphene oxide (rGO) as a battery cathode. The successful synthesis of rGO was verified through multiple characterization techniques. X-Ray Diffraction (XRD) analysis revealed an amorphous rGO structure with a peak at 25°. Fourier Transform Infrared Spectroscopy (FTIR) identified functional groups such as O-H, C=O, C=C, and C-O, with the presence of C=C bonds indicating the main structural component of rGO. Additionally, Scanning Electron Microscopy with Energy Dispersive X-Ray Spectroscopy (SEM-EDS) Mapping showed that the rGO 600 sample exhibited the highest porosity and carbon (C) composition, with a porosity value of 69.19% and a carbon content of 80.26%. Furthermore, the electrochemical performance of the battery was evaluated using Cyclic Voltammetry (CV). The results indicated that as the carbonization temperature increased (rGO 600), the CV curve exhibited a broader quasi-rectangular shape. Based on these findings, the rGO 600 sample derived from coalite exhibits significant potential as a material for sustainable battery development.
[1] H. Aprida, S. Hidayat, N. Syakir, R. Siregar, and Fitrilawati, "Electrical and Electrochemical Properties of Reduced Graphene Oxide Film for Secondary Battery Electrode," J. Phys.: Conf. Ser., vol. 1080, p.012032, Aug. 2018.
[2] Y. Mussa, F. Ahmed, M. Arsalan, and E. Alsharaeh, "Two Dimensional (2D) Reduced Graphene Oxide (RGO)/Hexagonal Boron Nitride (h-BN) Based Nanocomposites as Anodes for High Temperature Rechargeable Lithium-Ion Batteries," Sci Rep, vol. 10, no. 1, p.1882, Feb. 2020.
[3] X. Wang et al., "Improved Electrochemical Performance Based on Nanostructured SnS2@CoS2–rGO Composite Anode for Sodium-Ion Batteries," Nano-Micro Lett., vol. 10, no. 3, p.46, Jul. 2018.
[4] A. Pramanik, S. Chattopadhyay, G. De, and S. Mahanty, "Design of Cuboidal FeNi2S4-rGO-MWCNTs Composite for Lithium-Ion Battery Anode Showing Excellent Half and Full Cell Performances," Batteries, vol. 8, no. 12, p.261, Nov. 2022.
[5] B. Denis Louis Campéon, Y. Yoshikawa, T. Teranishi, and Y. Nishina, "Sophisticated rGO Synthesis and Pre-Lithiation Unlocking Full-Cell Lithium-Ion Battery High-Rate Performances," Electrochimica Acta, vol. 363, p.137257, Dec. 2020.
[6] J. Ginting, E. Yulianti, and Sudaryanto, "Sintesis Li2TiO3 sebagai Bahan Anoda Baterai Li-ion degan Metode Reaksi Padatan," J. Sains Mater. Indones., vol. 15, no. 4, p.196–200, 2014.
[7] A. F. Ramdja, A. Kurniawan, and S. Ahmad, "Manufacture of Activated Carbon from Coalite and its Application in Liquid Waste Treatment of Jumputan Fabric Industry," vol. 15, no. 4, 2008.
[8] A. Saleh, F. A. Amhadin, and I. Novianty, "Synthesis of Reduced Graphene Oxide and Zinc Oxide Composite from Candlenut Shell Charcoal (Aleuritas Moluccana)," ekw, vol. 8, no. 1, p.1, Jun. 2022.
[9] Inamuddin and A. M. Asiri, Eds., "Applications of Nanotechnology for Green Synthesis. in Nanotechnology in the Life Sciences". Cham: Springer International Publishing, 2020.
[10] E. Jaafar, M. Kashif, S. K. Sahari, and Z. Ngaini, "Study on Morphological, Optical and Electrical Properties of Graphene Oxide (GO) and Reduced Graphene Oxide (rGO)," MSF, vol. 917, p.112–116, Mar. 2018.
[11] A. Razaq, F. Bibi, X. Zheng, R. Papadakis, S. H. M. Jafri, and H. Li, "Review on Graphene-, Graphene Oxide-, Reduced Graphene Oxide-Based Flexible Composites: From Fabrication to Applications," Materials, vol. 15, no. 3, p.1012, Jan. 2022.
DOI: 10.3390/ma15031012
[12] S. Rani and M. Tomar, "Reduced Graphene Oxide (rGO) and its Composites: Synthesis and Applications".
[13] N.I. Ciptasari et al., "Synthesis of Nanocomposites Reduced Graphene Oxide-Silver Nanoparticles Prepared by Hydrothermal Technique Using Sodium Borohydride as a Reductor for Photocatalytic Degradation of Pb Ions in Aqueous Solution," EEJET, vol. 6, no. 5 (120), p.54–62, Dec. 2022.
[14] N. Bano, I. Hussain, A. M. EL-Naggar, and A. A. Albassam, "Reduced Graphene Oxide Nanocomposites for Optoelectronics Applications," Appl. Phys. A, vol. 125, no. 3, p.215, Mar. 2019.
[15] L. Buasuwan, V. Niyomnaitham, and A. Tandaechanurat, "Reduced Graphene Oxide Using an Environmentally Friendly Banana Extracts," MRS Advances, vol. 4, no. 38–39, p.2143–2151, Aug. 2019.
DOI: 10.1557/adv.2019.280
[16] A. T. Habte and D. W. Ayele, "Synthesis and Characterization of Reduced Graphene Oxide (rGO) Started from Graphene Oxide (GO) Using the Tour Method with Different Parameters," Advances in Materials Science and Engineering, vol. 2019, p.1–9, Aug. 2019.
DOI: 10.1155/2019/5058163
[17] A. Sjahriza and S. Herlambang, "Synthesis of Graphene Oxide from Coconut Shell Charcoal for Antibacterial and Antioxidant Applications," AK, vol. 8, no. 2, p.51–58, Dec. 2021.
[18] J. C. Silva Filho, E. C. Venancio, S. C. Silva, H. Takiishi, L. G. Martinez, and R. A. Antunes, "A Thermal Method for Obtention of 2 to 3 Reduced Graphene Oxide Layers from Graphene Oxide," SN Appl. Sci., vol. 2, no. 8, p.1450, Aug. 2020.
[19] N. Cao and Y. Zhang, "Study of Reduced Graphene Oxide Preparation by Hummers' Method and Related Characterization," Journal of Nanomaterials, vol. 2015, p.2–2, Jan 2015
DOI: 10.1155/2015/168125
[20] M. Strankowski, D. Włodarczyk, Ł. Piszczyk, and J. Strankowska, "Polyurethane Nanocomposites Containing Reduced Graphene Oxide, FTIR, Raman, and XRD Studies," Journal of Spectroscopy, vol. 2016, p.1–6, Aug 2016.
DOI: 10.1155/2016/7520741
[21] S. Abdolhosseinzadeh, H. Asgharzadeh, dan H. Seop Kim, "Fast and Fully-Scalable Synthesis of Reduced Graphene Oxide," Scientific Reports, vol. 5, no. 1, p.10160, May 2015
DOI: 10.1038/srep10160
[22] D. Chen, H. Feng, and J. Li, "Graphene Oxide: Preparation, Functionalization, and Electrochemical Applications," Chem. Rev., vol. 112, no. 11, p.6027–6053, Nov. 2012.
DOI: 10.1021/cr300115g
[23] M. S. Khan, R. Yadav, R. Vyas, A. Sharma, M. K. Banerjee, and K. Sachdev, "Synthesis and Evaluation of Reduced Graphene Oxide for Supercapacitor Application," Mater. Today Proc., vol. 30, no. xxxx, p.153–156, 2020.
[24] S. C. Rodrigues, M. C. Silva, J. A. Torres, and M. L. Bianchi, "Use of Magnetic Activated Carbon in a Solid Phase Extraction Procedure for Analysis of 2,4-dichlorophenol in Water Samples," Water Air Soil Pollut, vol. 231, no. 6, p.294, Jun. 2020.
[25] N. Kristiyanti and W. S. B. Dwandaru, "Sintesis dan Karakterisasi Reduced Graphene Oxide Berbahan Dasar Karbon Baterai NMC Menggunakan Metode Audiosonikasi".
[26] F. Astuti, N. Sari, V. L. Maghfirohtuzzoimah, R. Asih, M. A. Baqiya, and D. Darminto, "Study of the Formation of Amorphous Carbon and rGO-like Phases from Palmyra Sugar by Variation of Calcination Temperature," JFA, vol. 16, no. 2, p.91, Jun. 2020.
[27] B. Gupta, N. Kumar, K. Panda, V. Kanan, S. Joshi, and I. Visoly-Fisher, "Role of Oxygen Functional Groups in Reduced Graphene Oxide for Lubrication," Sci Rep, vol. 7, no. 1, p.45030, Mar. 2017.
DOI: 10.1038/srep45030
[28] B. A. Gaweł, A. Ulvensøen, K. Łukaszuk, B. Arstad, A. M. F. Muggerud, and A. Erbe, "Structural Evolution of Water and Hydroxyl Groups during Thermal, Mechanical and Chemical Treatment of High Purity Natural Quartz," RSC Adv., vol. 10, no. 48, p.29018–29030, 2020.
DOI: 10.1039/D0RA05798C
[29] I. Bagherpour, A. Yaghtin, S. M. Naghib, and F. Molaabasi, "Synthesis and Investigation on Microstructural, Mechanical Features of Mesoporous Hardystonite/Reduced Graphene Oxide Nanocomposite for Medical Applications," Front. Bioeng. Biotechnol., vol. 11, p.1073435, Mar. 2023.
[30] A. Shalaby, D. Nihtianova, P. Markov, A. D. Staneva, R. S. Iordanova, and Y. B. Dimitriev, "Structural Analysis of Reduced Graphene Oxide by Transmission Electron Microscopy".
[31] W. Zhu et al., "Structure and Electronic Transport in Graphene Wrinkles," Nano Lett., vol. 12, no. 7, p.3431–3436, Jul. 2012.
DOI: 10.1021/nl300563h
[32] V. C. Saha et al., "Synthesis and Characterization of Reduced Graphene Oxide Reinforced Polymer Matrix Composite," IOP Conf. Ser.: Mater. Sci. Eng., vol. 438, p.012008, Oct. 2018.
[33] W. Ullya and R. Jonuarti, "Effect of Calcination Temperature on Microstructure, Porosity and Hardness of CaO/SiO2 Nanocomposites for Bone Implants".
[34] N. A. Ogolo, O. G. Akinboro, J. E. Inam, F. E. Akpokere, and M. O. Onyekonwu, "Effect of Grain Size on Porosity Revisited," in All Days, Lagos, Nigeria: SPE, Aug. 2015, p. SPE-178296-MS.
DOI: 10.2118/178296-MS
[35] W. Qu et al., "Effect of Temperature Gradient on the Grain Size Homogeneity of SEED Produced Semi-Solid Slurries by Phase-Field Simulation," Materials, vol. 12, no. 20, p.3309, Oct. 2019.
DOI: 10.3390/ma12203309
[36] A. Noor, M. Hamdini, S. Ramadina, and Y. Tiandho, "Dye-Sensitized Solar Cell-Based Photovoltaic Thermal for Ethanol Distillation: A Narrative Review," jgs, vol. 8, no. 2, p.123, Jan. 2021.
[37] S. A. Borghei et al., "Synthesis of Multi-Application Activated Carbon from Oak Seeds by KOH Activation for Methylene Blue Adsorption and Electrochemical Supercapacitor Electrode," Arabian Journal of Chemistry, vol. 14, no. 2, p.102958, Feb. 2021.
[38] W. S. Arsyad, Y. Pranata, V. I. Variani, I. Usman, L. Aba, and L. Agusu, "Synthesize of rGO from Coal (Sub-Bituminous) as a Counter-Electrode on Dye-Sensitized Solar Cells," J. Phys.: Conf. Ser., vol. 1951, no. 1, p.012005, Jun. 2021.
[39] M. Diantoro, I. Istiqomah, Y. Al. Fath, N. Nasikhudin, and W. Meevasana. 2023. Potential of MnO2-Based Composite and Numerous Morphological for Enhancing Supercapacitors Performance. International Journal of Applied Ceramic Technology, 1–22.
DOI: 10.1111/ijac.14377
[40] C. C. Lee, F. S. Omar, A. Numan, N. Duraisamy, K. Ramesh, and S. Ramesh, "An Enhanced Performance of Hybrid Supercapacitor Based on Polyaniline-Manganese Phosphate Binary Composite," J Solid State Electrochem, vol. 21, no. 11, p.3205–3213, Nov. 2017.